Significance and Use

Chlorinated compounds can lead to corrosion of equipment and poisoning of the catalyst. Chlorinated compounds also present a health hazard when incompletely combusted. Chlorine content of petroleum products is determined prior to their being recycled.

Note 1Federal Regulations mandate that often the chlorine content of used oil must be determined before recycling.

These test methods can be used to determine when a used petroleum product meets or exceeds requirements for total halogens measured as chloride. It is specifically designed for used oils, permitting on-site testing at remote locations by nontechnical personnel to avoid the delays of laboratory testing.

1. Scope

1.1 These test methods cover the determination of chlorine in used oils, fuels, and related materials, including: crankcase, hydraulic, diesel, lubricating and fuel oils, and kerosene, all containing <25 % (mass/mass) water.

1.1.1 Bromide and iodide are also titrated and reported on a molar basis as chlorine.

1.2 The entire analytical sequence, including sampling, sample pretreatment, chemical reactions, extraction, and quantification, is available in kit form using predispensed and encapsulated reagents. The overall objective is to provide a simple, easy to use procedure, permitting nontechnical personnel to perform a test in or outside of the laboratory environment in under 10 min. The test method also gives information to run the test without a kit.

1.2.1 Test Method A is preset to provide a greater than or less than result at 1000 mg/kg (ppm) total chlorine to meet regulatory requirements for used oils.

1.2.2 Test Method B provides results over a range from 200 to 4000 mg/kg total chlorine.

1.3 For both test methods, positive bias will result from samples that contain greater than 3 % (mass/mass) total sulfur. While a false negative result will not occur, other analytical methods should be used on high sulfur oils.

1.4 Test Method B, Lower Limit of Quantitation In the round-robin study to develop statistics for this test method, participants were asked to report results to the nearest 100 mg/kg. The lower limit of quantification could therefore only be determined to be in the range from 870 to 1180 mg/kg ⁵ .

1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific safety statements are given in Sections 3, 6, and 7.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

Keywords

chlorine; field test; halogen; on-site testing; test kit; used oil;

ICS Code

ICS Number Code 75.080 (Petroleum products in general)

DOI: 10.1520/D5384-11

ASTM International is a member of CrossRef.

ASTM D5384