Significance and Use

This guide is intended as a means for selecting the proper methods for measuring cyanide to conform to the International Cyanide Management Code guidance related to the analysis of cyanide bearing solutions. Cyanide is analyzed in process solutions and in discharges in order to apply code guidance; however, improper sample collection and preservation can result in significant positive or negative bias, potentially resulting in over reporting or under reporting cyanide releases into the environment.

This guide contains comparative test methods that are intended for use in routine monitoring of cyanide. It is assumed that all who use methods listed in this guide will be trained analysts capable of performing them skillfully and safely. It is expected that work will be performed in a properly equipped laboratory applying appropriate quality control practices such as those described in Guide .

1. Scope

1.1 This guide is applicable for the selection of appropriate ASTM standard analytical methods for metallurgical processing sites to conform to International Cyanide Management Code guidance for the analysis of cyanide bearing solutions.

1.2 The analytical methods in this practice are recommended for the sampling preservation and analysis of total cyanide, available cyanide, weak acid dissociable cyanide, and free cyanide by Test Methods , , , , , , , and . The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3 This guide does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard guide to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D1129 Terminology Relating to Water

D1193 Specification for Reagent Water

D1293 Test Methods for pH of Water

D1976 Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy

D2036 Test Methods for Cyanides in Water

D3694 Practices for Preparation of Sample Containers and for Preservation of Organic Constituents

D3856 Guide for Management Systems in Laboratories Engaged in Analysis of Water

D4282 Test Method for Determination of Free Cyanide in Water and Wastewater by Microdiffusion

D4374 Test Methods for Cyanides in Water--Automated Methods for Total Cyanide, Weak Acid Dissociable Cyanide, and Thiocyanate

D4840 Guide for Sample Chain-of-Custody Procedures

D4841 Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents

D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D6696 Guide for Understanding Cyanide Species

D6888 Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection

D6994 Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection

D7237 Test Method for Free Cyanide with Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection

D7284 Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection

D7365 Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide

D7511 Test Method for Total Cyanide by Segmented Flow Injection Analysis, In-Line Ultraviolet Digestion and Amperometric Detection

D7572 Guide for Recovery of Aqueous Cyanides by Extraction from Mine Rock and Soil After Remediation of Process Releases

Keywords

free cyanide; International Cyanide Management Code; WAD cyanide;

ICS Code

ICS Number Code 71.040.40 (Chemical analysis)

DOI: 10.1520/D7728-11

ASTM International is a member of CrossRef.

ASTM D7728